Illustrations of two compounds made from phosphorus atoms (orange) and hydrogen atoms (white). Such compounds are potential superconductors, and may form when phosphine is squeezed under extremely high pressures, according to University at Buffalo chemists who predicted the compounds’ structures using XtalOpt, an open-source computer program created at UB. Credit: Tyson Terpstra Phosphine is one of the newest materials to be named a superconductor, a material through which electricity can flow with zero resistance. In 2015, scientists reported that they had liquefied the chemical and squeezed it under high pressure in a diamond vise to achieve superconductivity.
Now, a different group of researchers is providing insight into what may have happened to the phosphine as it underwent this intense compression.
University at Buffalo chemists say that according to their calculations, phosphine’s superconductivity under pressure likely arose due to the compound decomposing into other chemical products that contain phosphorus and hydrogen.
”So it’s probably a mix of these decomposition products—and not phosphine itself—that results in the superconductivity observed in experiments,” says Eva Zurek, PhD, an associate professor of chemistry in the UB College of Arts and Sciences.
The findings could assist scientists in their quest to find or create new commercially feasible superconductors, which are sought after because the materials transmit energy with ultra-high efficiency, losing no energy and giving off no heat, she says.
”In experiments where high pressures are involved, it’s difficult for scientists to characterize what materials they’ve created,” Zurek says. ”But understanding what’s actually there is important because it gives us an idea of how we might go about making new superconducting compounds.”
The new study was published on Jan. 16 in the Journal of the American Chemical Society as a Just Accepted Manuscript and will appear in a future print edition of the journal.
Breaking things down (literally)
At room temperature, phosphine is composed of one atom of phosphorus (P) and three of hydrogen (H).
But the UB researchers calculated that under pressure, PH3 becomes unstable and likely breaks down into structures that include PH2, PH and PH5, which are more stable.
Zurek’s team used XtalOpt, an open-source computer program that one of her former students created, to understand which combinations of phosphorus and hydrogen were stable at pressures of up to 200 gigapascals—nearly 2 million times the pressure of our atmosphere here on Earth, and similar to the pressure at which phosphine was squeezed in the diamond vise in the superconductor experiment.
The search for superconductors
One reason researchers are so keen on finding new superconductors is that the only known superconductors are superconducting only at extremely low temperatures (well below freezing), which complicates practical applications and makes their maintenance extremely difficult.
Interest in the field has intensified over the past year, since a team led by scientist Mikhail Eremets smashed previous temperature records by finding that a hydrogen and sulfur compound squeezed under 150 gigapascals of pressure was a superconductor at 203 degrees Kelvin, about -94 degrees Fahrenheit. That may seem cold, but it’s a lot warmer than past thresholds.
Eremets and his colleagues were also the group that conducted the experiment on phosphine, with superconductivity observed at temperatures higher than 100 Kelvin (roughly -280 degrees Fahrenheit).
”Finding materials that are superconducting at high temperatures would revolutionize our electric power infrastructure, because virtually no energy would be wasted during transmission and distribution through superconducting wires,” Zurek said. ”In addition, superconducting magnets could be employed for high-speed levitating trains (maglev) that move more smoothly and efficiently than wheeled trains. These technologies exist nowadays, but the superconductors must be cooled to very low temperatures for them to work.”
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More information: Andrew Shamp et al. Decomposition Products of Phosphine Under Pressure: PH2 Stable and Superconducting?, Journal of the American Chemical Society (2016). DOI: 10.1021/jacs.5b10180
Journal reference:Journal of the American Chemical Society
Provided by:University at Buffalo